Silicon carbide, more commonly referred to as Carborundum or SiC, is a hard ceramic material with numerous applications. This versatile substance serves as abrasives, has wide bandgap semiconductor properties and can even be fabricated into structural ceramic components.
Production involves reacting and pyrolyzing polysiloxanes under pressure, ground into powder form, sinterding to form solid shapes, then grinding for final microstructural shaping. Each step plays an integral part in producing this final material with different results depending on forming methods used – with these having significant bearing on microstructure.
Theoretical Density
Silicon carbide’s dense composition plays a key role in its ability to resist chemical, thermal and mechanical stress. With superior hardness and thermal conductivity properties, silicon carbide makes an excellent material choice for high performance and high stress applications.
Denser materials tend to offer greater resistance against corrosion and wear. Furthermore, their low expansion/shrinking rates enable them to better withstand temperature extremes – making them ideal for electrical and gas systems.
SiC is also highly resistant to radiation and has an unusually large bandgap compared with other semiconductors, enabling it to operate at much higher temperatures, voltages and frequencies compared with its peers. SiC can therefore be found used across a variety of electronics and industrial applications including power generation, aerospace and automotive use.
Reaching high densities of SiC can be challenging for large components. But with ramp compression technology, achieving uniform densities of up to 98% of theoretical density has now become possible. The process involves creating a homogenous dispersion of submicron-sized powder mixture consisting primarily of silicon carbide with an additive containing boron; then shaping this powder mixture into green bodies before sintered at 1900deg-2100deg C under controlled atmosphere conditions.
Boron-containing additives should be added during powder mixing in an amount equivalent to one part by weight of elemental boron per 100 parts of silicon carbide, for safe densification without segregation at grain boundaries.
Physical Density
Silicon carbide (C-Si) is an artificial material composed of carbon (C) and silicon (Si). It has the second-hardest Mohs hardness rating after boron carbide at 9 and offers exceptional strength, resistance to wear and corrosion resistance; in fact it can even withstand exposure to hydrofluoric and sulphuric acids without becoming corroded – plus water, most chemicals including alkalis cannot dissolve it! Silicon carbide’s versatility as an engineering material also makes it popular with scientists.
As it can withstand high-speed cutting and grinding operations, as well as being used for abrasive blasting and machining applications, emery is widely utilized for modern lapidary work due to its durability and cost effectiveness. Furthermore, it serves as an important raw material in producing grinding and polishing compounds.
Silicon carbide has emerged as a primary material of space technology due to its outstanding durability and radiation-level resistance. As such, mirrors made out of silicon carbide have become the choice of several of the largest telescopes such as Herschel and BepiColombo missions, or can even be fashioned into rigid frames to withstand temperatures found on Venus and radiation levels that exceed expectations.
Recent experimental evidence demonstrates that a-SiC is stable in its B1 phase over an extensive range of conditions that correspond with expected mantle conditions of carbon-rich exoplanets, in contrast to its behavior on Earth where it decomposes rapidly into silica and oxygen.
Chemical Density
Silicon carbide, more commonly referred to as SiC, is a chemical compound composed of silicon (atomic number 14) and carbon (atomic number 6). It features an iridescent green to bluish black appearance with noncombustibility features; its density stands at 3.21 grams per cubic cm3.
Silicon carbide occurs naturally in meteorites, corundum deposits and kimberlite deposits in limited amounts; however, most silicon carbide used in electronic devices is produced synthetically. Edward Acheson first synthesized silicon carbide synthetically in 1891 when he attempted to create artificial diamonds by heating clay and powdered coke in an electric arc furnace; when doing this he noticed bright green crystals that looked similar to diamond attached to carbon electrodes and named these crystals “moissanite” after the type of stone it resembled.
SiC is a semiconductor material with an extremely wide band gap, enabling it to operate at higher temperatures and voltages than other semiconductor materials. Due to its excellent thermal conductivity, heat dissipation occurs quickly while its dense crystalline structure provides superior wear resistance – perfect for applications such as cutting tools.
EAG Laboratories has extensive experience analyzing SiC using both bulk and spatially resolved analytical techniques. SiC is an extremely useful material for manufacturing semiconductors as it can be doped with various elements to alter its electrothermal characteristics. Assuring concentration and spatial distribution of dopants while eliminating undesirable contaminants is paramount in creating high-quality semiconductor products.
Thermal Density
Silicon carbide is an extremely dense material and one of the hardest substances available, providing excellent corrosion resistance as a ceramic material that could possibly reduce active cooling systems in electric vehicles.
Silicon Carbide (SiC) is a covalently bonded light gray solid with the relative hardness of diamond on the Mohs scale. Refractories possessing these properties are ideal for use as SiC has high melting point, thermal conductivity and low thermal expansion rates.
Silicon Carbide can be doped with nitrogen or phosphorus to form an n-type semiconductor; or doped with beryllium, boron, aluminum and gallium to make a p-type semiconductor. Because of its wide bandgap that enables it to handle three times higher voltage than standard silicon semiconductors. Silicon Carbide has become the go-to material for electronic device production due to its broad usage as an electronic component material.
Natural SiC deposits exist in certain meteorite samples, corundum deposits and kimberlite, but most industrial SiC is synthetically produced. SSiC and SiSiC variants are among the most frequently utilized materials for demanding conditions like 3D printing, ballistics production, chemical production and energy technology applications as well as pipe system components due to their thermal properties; their higher density than pure quartz makes these compounds an appealing metal replacement and they offer good stiffness, hardness and high temperature resistance properties that rival pure quartz’s thermal properties compared with pure quartz and high temperature resistance making these compounds attractive metal replacement alternatives.